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actress is dating her costar Tim Daly, who plays the husband of her character Elizabeth Faulkner Mc Cord on the CBS political drama.

PHOTOS: Costar couples "Their chemistry on set is electrifying," a source tells Us of Leoni, 48, and Daly, 58.

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They split in June 2011 and finalized their divorce this past August.

Tim was married to Amy Van Nostrand from 1982 to 2010.

PHOTOS: Celeb couples and how they met "She's not a whiner. I've gotten along with plenty of people, but the chemistry sucked.is reporting that co-stars Tea Leoni and Tim Daly, who play married couple Elizabeth and Henry Mc Cord on the CBS drama, are now an item both on-screen and off.2014 Fall TV Report Card: How's the new class doing?She wants to work hard and she wants to have fun," he added. And I've hated people where the chemistry is great.It's much better if you get along and the chemistry is good.